FURTHER MEASUREMENTS OF THE ROTATIONAL SPECTRUM OF COF2 - IMPROVED MOLECULAR-CONSTANTS FOR THE GROUND AND NU-2 STATES

被引：14

作者：

COHEN, EA ^{[1
]}

LEWISBEVAN, W ^{[1
]}

机构：

[1] SO ILLINOIS UNIV,DEPT CHEM & BIOCHEM,CARBONDALE,IL 62901

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1991年 / 148卷 / 02期

关键词：

D O I：

10.1016/0022-2852(91)90394-P

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

Additional measurements of the rotational spectrum of COF2 in the 200-600 GHz region have led to improved rotational parameters for the ground vibrational state. These parameters have been used in refitting the ν2 infrared spectrum near 963 cm-1. Results using both Ir A and IIIr S Watson reduced Hamiltonians are presented. The new upper state parameters reproduce recently measured FIR laser frequencies with an RMS of 0.25 MHz. © 1991.

引用

页码：378 / 384

页数：7

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