Chemical free energies of solvation of single ions in different solvents and the hard-soft classification

被引：7

作者：

Lohmann, F. ^{[1
]}

机构：

[1] Cyanamid European Res Inst, Geneva, Switzerland

来源：

CHEMICAL PHYSICS LETTERS | 1968年 / 2卷 / 08期

关键词：

D O I：

10.1016/0009-2614(63)80045-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The standard chemical free energies of solvation of single ions mu(s)(1) in water and acetonitrile are compared. The parameter (mu(H2O)(i) - mu(CH3CN)(i))/mu(H2O)(i) parallels essentially the parameter of Pearson and Mawby and other parameters of softness.

引用

页码：659 / 660

页数：2

共 14 条

[1] Scales of softness for acceptors and donors [J].

Ahrland, S. .

CHEMICAL PHYSICS LETTERS, 1968, 2 (05) :303-306

[2]

Arland S, 1968, STRUCT BOND, V5, P118, DOI [10.1007/BFb0118849, DOI 10.1007/BFB0118849]

[3] REAL SOLVATION ENERGIES OF HYDROCARBON IONS IN ACETONITRILE AND SURFACE POTENTIAL OF ACETONITRILE [J].

CASE, B ;

HUSH, NS ;

PARSONS, R ;

PEOVER, ME .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1965, 10 (5-6) :360-&

[4] REAL FREE ENERGIES OF SOLVATION OF IONS IN SOME NON-AQUEOUS AND MIXED SOLVENTS [J].

CASE, B ;

PARSONS, R .

TRANSACTIONS OF THE FARADAY SOCIETY, 1967, 63 (533P) :1224-&

[5]

IZMAILOV NA, 1963, P ACAD SCI USSR, V149, P348

[6] CHEMICAL REACTIVITY AND CONCEPT OF CHARGE- AND FRONTIER-CONTROLLED REACTIONS [J].

KLOPMAN, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (02) :223-&

[7]

Moelwyn-Hughes E.A., 1957, PHYS CHEM, P373

[8] THE EFFECTS OF SOLVATION ON THE PROPERTIES OF ANIONS IN DIPOLAR APROTIC SOLVENTS [J].

PARKER, AJ .

QUARTERLY REVIEWS, 1962, 16 (02) :163-187

[9]

Parsons R., 1954, MODERN ASPECTS ELECT, V1

[10] HARD AND SOFT ACIDS AND BASES [J].

PEARSON, RG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1963, 85 (22) :3533-&

← 1 2 →