New Route to Hybrid Materials: Rhodium Complex and Fluoride Ion Catalysed Hydrolysis of Hydrogenosilanes

被引：28
作者：
Corriu, Robert J. P. [1 ]
Moreau, Joel J. E. [1 ]
Man, Michel Wong Chi [1 ]
机构：
[1] Univ Montpellier 2, Unite Mixte CNRS RP USTL 44, Sci & Tech Languedoc, F-34095 Montpellier 05, France
来源：
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY | 1994年 / 2卷 / 1-3期
关键词：
polyorganosilsesquioxane trihydrosilane; hydrolytic condensation; solid state Si-29 NMR;
D O I：
10.1007/BF00486218
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
An alternative route to organosilsesquioxanes by hydrolytic condensation of the Si-H bonds of trihydrosilanes is described. This method avoids the formation of alcohols or acids since the leaving group is removed as hydrogen gas. The influence of the catalyst, ClRh(PPh3)(3) or fluoride anion, on the properties of the resulting materials is discussed.
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收藏
页码：87 / 91
页数：5
相关论文
共 18 条
[1]   CONVERSION OF HYDROSILANES TO ALKOXYSILANES CATALYZED BY CP2TICL2/NORMAL-BULI [J].
BEDARD, TC ;
COREY, JY .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 428 (03) :315-333
[2]  
Brinker C.J., 1990, SOL GEL SCI PHYS CHE
[3]  
Cerveau G., J NONCRYST IN PRESS
[4]  
CHUNG YJ, 1990, MATER RES SOC SYMP P, V180, P981, DOI 10.1557/PROC-180-981
[5]   PREPARATION OF MONOLITHIC BINARY OXIDE GELS BY A NONHYDROLYTIC SOL-GEL PROCESS [J].
CORRIU, R ;
LECLERCQ, D ;
LEFEVRE, P ;
MUTIN, PH ;
VIOUX, A .
CHEMISTRY OF MATERIALS, 1992, 4 (05) :961-963
[6]  
Corriu R.J.P., 1973, J CHEM SOC CHEM COMM, V38
[7]  
Corriu R.J.P., 1989, CHEM ORGANIC SILICON
[8]   PREPARATION OF MONOLITHIC GELS FROM SILICON HALIDES BY A NONHYDROLYTIC SOL-GEL PROCESS [J].
CORRIU, RJP ;
LECLERCQ, D ;
LEFEVRE, P ;
MUTIN, PH ;
VIOUX, A .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1992, 146 (2-3) :301-303
[9]   ACTIVATION OF SILICON HYDROGEN, SILICON OXYGEN, SILICON NITROGEN BONDS IN HETEROGENEOUS PHASE - SOME NEW METHODS IN ORGANIC-SYNTHESIS [J].
CORRIU, RJP ;
PERZ, R ;
REYE, C .
TETRAHEDRON, 1983, 39 (06) :999-1009
[10]   NEW MIXED ORGANIC INORGANIC POLYMERS - HYDROLYSIS AND POLYCONDENSATION OF BIS(TRIMETHOXYSILYL)ORGANOMETALLIC PRECURSORS [J].
CORRIU, RJP ;
MOREAU, JJE ;
THEPOT, P ;
MAN, MWC .
CHEMISTRY OF MATERIALS, 1992, 4 (06) :1217-1224
12