ON THE FORMATION OF BIACETYL TRIMERS IN ACIDIC MEDIA

被引:5
作者
BALDENIUS, K [1 ]
DALLMAN, P [1 ]
HUDEC, J [1 ]
机构
[1] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO9 5NH,HANTS,ENGLAND
关键词
D O I
10.1016/S0040-4039(00)60334-9
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Evidence is presented to show that the tricyclic trimer of biacetyl (1) is formed in acidic media via ''biacetyl hydrates'' rather than the dimeric aldol (2). A new trimer (3) has been isolated as well as a crystalline biacetyl trimer dihydrate.
引用
收藏
页码:1517 / 1520
页数:4
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