ENZYME-CATALYZED REACTIONS .13. A NEW, EFFICIENT SYNTHESIS OF FAGOMINE

被引：0

作者：

EFFENBERGER, F

NULL, V

机构：

来源：

LIEBIGS ANNALEN DER CHEMIE | 1992年 / 11期

关键词：

FAGOMINE; ENZYMES; TRANSKETOLASE; CARBOHYDRATES; YEAST TRANSKETOLASE;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

2-Deoxy-L-threo-5-hexulosonitrile (4) is obtained in excellent chemical yield by yeast transketolase (EC 2.2.1.1)-catalyzed reaction of racemic 3-hydroxy-4-oxobutyronitrile [(R/S)-2] with lithium hydroxypyruvate (3). Catalytic hydrogenation of 4 exclusively gives fagomine (7).

引用

页码：1211 / 1212

页数：2

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