ENZYME-CATALYZED REACTIONS .13. A NEW, EFFICIENT SYNTHESIS OF FAGOMINE

被引：0
|
作者：
EFFENBERGER, F
NULL, V
机构：
来源：
LIEBIGS ANNALEN DER CHEMIE | 1992年 / 11期
关键词：
FAGOMINE; ENZYMES; TRANSKETOLASE; CARBOHYDRATES; YEAST TRANSKETOLASE;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
2-Deoxy-L-threo-5-hexulosonitrile (4) is obtained in excellent chemical yield by yeast transketolase (EC 2.2.1.1)-catalyzed reaction of racemic 3-hydroxy-4-oxobutyronitrile [(R/S)-2] with lithium hydroxypyruvate (3). Catalytic hydrogenation of 4 exclusively gives fagomine (7).
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页码：1211 / 1212
页数：2
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