TRIMETHYLSILYLATION OF PROPARGYL CHLORIDE AND PROPARGYL BROMIDE

被引：14
|
作者：
VERKRUIJSSE, HD [1 ]
BRANDSMA, L [1 ]
机构：
[1] UNIV UTRECHT,DEBYE INST,DEPT PREPARAT ORGAN CHEM,PADUALAAN 8,3584 CH UTRECHT,NETHERLANDS
来源：
SYNTHETIC COMMUNICATIONS | 1990年 / 20卷 / 21期
关键词：
D O I：
10.1080/00397919008051574
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Me3SiC = CCH2Cl and Me3SiC = CCH2Br are obtained in high yields by treating propargyl chloride and bromide, respectively, with n-butyllithium and lithium diisopropylamide and subsequently adding chlorotrimethylsilane in the presence of hexamethylphosphoric triamide (HMPT). An effective method for the purification of HMPT is described.
引用
收藏
页码：3375 / 3378
页数：4
相关论文
共 50 条
  • [1] Photodissociation of propargyl bromide and photoionization of the propargyl radical
    Fan, H
    Pratt, ST
    JOURNAL OF CHEMICAL PHYSICS, 2006, 124 (14):
  • [2] The electron diffraction investigation of propargyl chloride, bromide, and iodide
    Pauling, L
    Gordy, W
    Saylor, JH
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1942, 64 : 1753 - 1756
  • [3] PHOTOLYSIS + RADIOLYSIS OF PROPARGYL BROMIDE
    TRACHTMAN, M
    JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (06): : 1415 - &
  • [4] AN UNUSUAL REACTION OF PROPARGYL BROMIDE
    ZAUGG, HE
    SWETT, LR
    STONE, GR
    JOURNAL OF ORGANIC CHEMISTRY, 1958, 23 (09): : 1389 - 1390
  • [5] Investigation of Pyridine/Propargyl Bromide Reaction and Strong Fluorescence Enhancements of the Resultant Poly(propargyl pyridinium bromide)
    Zhou, Changming
    Gao, Yong
    Chen, Daoyong
    JOURNAL OF PHYSICAL CHEMISTRY B, 2012, 116 (37): : 11552 - 11559
  • [6] SYNTHESIS OF SOLUBLE POLY(PROPARGYL-BROMIDE) AND POLY(PROPARGYL-CHLORIDE) BY TRANSITION-METAL CHLORIDES AND ETHYLALUMINUM DICHLORIDE
    WON, CL
    JIN, ES
    YEONG, SG
    SAM, KC
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 1988, 9 (05) : 328 - 329
  • [7] A REINVESTIGATION ON THE REACTION OF ANTHRONE WITH PROPARGYL BROMIDE
    MAJUMDAR, KC
    CHATTOPADHYAY, SK
    INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 1989, 28 (06): : 514 - 515
  • [8] Evaluation of propargyl bromide as a soil fumigant
    Zasada, Inga A.
    Elmore, Clyde L.
    Yakabe, Lani E.
    MacDonald, James D.
    HORTSCIENCE, 2007, 42 (05) : 1212 - 1216
  • [9] Characterization of propargyl bromide transformation in soil
    Papiernik, SK
    Gan, JY
    Yates, SR
    PEST MANAGEMENT SCIENCE, 2002, 58 (10) : 1055 - 1062
  • [10] Mechanism of degradation of methyl bromide and propargyl bromide in soil
    Papiernik, SK
    Gan, JY
    Yates, SR
    JOURNAL OF ENVIRONMENTAL QUALITY, 2000, 29 (04) : 1322 - 1328
12345