Reaction Kinetics of Carbon Dioxide and Glycidyl Methacrylate using a Ionic Liquid Catalyst of Imidazole Immobilized on MCM41

被引：0

作者：

Son, Young-Sik ^{[1
]}

Park, Moon-Ki ^{[2
]}

Kim, Gun-Woo ^{[3
]}

Park, Sang-Wook ^{[1
]}

机构：

[1] Pusan Natl Univ, Div Chem Engn, Busan 609735, South Korea

[2] Daegu Haany Univ, Dept Pharmaceut Engn, 290 Yugok Dong, Gyongsan 712715, Gyeongbuk, South Korea

[3] Small & Medium Business Adm, Busan Ulsan Reg Off, Business Environm Improvement Div, Busan 618819, South Korea

来源：

KOREAN CHEMICAL ENGINEERING RESEARCH | 2009年 / 47卷 / 04期

关键词：

Imidazole; Carbon Dioxide; Absorption; Ionic Liquid;

D O I：

暂无

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Carbon dioxide was absorbed into GMA solution in a stirred flat cell using mesoporous catalyst Imidazole-CP-MS41, which was synthesized by CP-MCM41 with imidazole. Experiments were carried out at a batch-type absorber with different conditions, varying reaction temperature, concentration of GMA, solvent but maintaining 50 rpm of agitation speed and 2 g of catalyst. Absorption rate of CO2 was used to obtain the kinetics based on the film theory using zwitterion mechanism with 2 elementary reaction and the kinetics were correlated with the solubility parameter of the solvents.

引用

页码：410 / 417

页数：8

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