Reaction Kinetics of Carbon Dioxide and Glycidyl Methacrylate using a Ionic Liquid Catalyst of Imidazole Immobilized on MCM41

被引：0
作者：
Son, Young-Sik [1 ]
Park, Moon-Ki [2 ]
Kim, Gun-Woo [3 ]
Park, Sang-Wook [1 ]
机构：
[1] Pusan Natl Univ, Div Chem Engn, Busan 609735, South Korea
[2] Daegu Haany Univ, Dept Pharmaceut Engn, 290 Yugok Dong, Gyongsan 712715, Gyeongbuk, South Korea
[3] Small & Medium Business Adm, Busan Ulsan Reg Off, Business Environm Improvement Div, Busan 618819, South Korea
来源：
KOREAN CHEMICAL ENGINEERING RESEARCH | 2009年 / 47卷 / 04期
关键词：
Imidazole; Carbon Dioxide; Absorption; Ionic Liquid;
D O I：
暂无
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Carbon dioxide was absorbed into GMA solution in a stirred flat cell using mesoporous catalyst Imidazole-CP-MS41, which was synthesized by CP-MCM41 with imidazole. Experiments were carried out at a batch-type absorber with different conditions, varying reaction temperature, concentration of GMA, solvent but maintaining 50 rpm of agitation speed and 2 g of catalyst. Absorption rate of CO2 was used to obtain the kinetics based on the film theory using zwitterion mechanism with 2 elementary reaction and the kinetics were correlated with the solubility parameter of the solvents.
引用
收藏
页码：410 / 417
页数：8
相关论文
共 34 条
[21]   Kinetic parameter estimation for 1,1,3,3-tetramethylguanidinum trifluoroacetate ionic liquid in the reaction of glycidyl methacrylate with carbon dioxide [J].
Sang-Wook Park ;
Byoung-Sik Choi ;
Dae-Won Park ;
Jae-Wook Lee .
Research on Chemical Intermediates, 2008, 34 :881-889
[22]   Cycloaddition of carbon dioxide to epichlorohydrin using ionic liquid as a catalyst [J].
Lee, Eun-Ha ;
Cha, So-Wan ;
Dharma, Manju Mamparambath ;
Choe, Youngson ;
Ahn, Ji-Yun ;
Park, Dae-Won .
KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2007, 24 (03) :547-550
[23]   Cycloaddition of carbon dioxide to epichlorohydrin using ionic liquid as a catalyst [J].
Eun-Ha Lee ;
So-Wan Cha ;
Manju Mamparambath Dharma ;
Youngson Choe ;
Ji-Yun Ahn ;
Dae-Won Park .
Korean Journal of Chemical Engineering, 2007, 24 :547-550
[24]   Chemical kinetics of the reaction between carbon dioxide and phenyl glycidyl ether using Aliquat 336 as a catalyst [J].
Park, SW ;
Park, DW ;
Kim, TY ;
Park, MY ;
Oh, KJ .
CATALYSIS TODAY, 2004, 98 (04) :493-498
[25]   A Novel Gemini Sulfonic Ionic Liquid Immobilized MCM-41 as Efficient Catalyst for Doebner-Von Miller Reaction to Quinoline [J].
Li, An ;
Wang, Xinyang ;
Li, Yuhang ;
Luo, Caiwu ;
Zhang, Jiance ;
Liu, Kun ;
Zhang, Cen ;
Zhou, Congshan .
CHEMCATCHEM, 2021, 13 (17) :3772-3780
[26]   Reaction kinetic for poly (styrene-co-vinylbenzyl chloride)-supported catalyst containing pendant tetraethylammonium chloride in the reaction of glycidyl methacrylate with carbon dioxide [J].
Park, S. W. ;
Choi, B. S. ;
Park, D. W. ;
Udayakumar, S. ;
Lee, J. W. .
CATALYSIS TODAY, 2008, 131 (1-4) :559-565
[27]   Role of TiO2 nanoparticle modification of Cr/MCM41 catalyst to enhance Cr-support interaction for oxidative dehydrogenation of ethane with carbon dioxide [J].
Al-Awadi, Abdulrhman S. ;
El-Toni, Ahmed Mohamed ;
Al-Zahrani, Saeed M. ;
Abasaeed, Ahmed E. ;
Alhoshan, Mansour ;
Khan, Aslam ;
Labis, Joselito P. ;
Al-Fatesh, Ahmed .
APPLIED CATALYSIS A-GENERAL, 2019, 584
[28]   Immobilized ionic liquid/zinc chloride: Heterogeneous catalyst for synthesis of cyclic carbonates from carbon dioxide and epoxides [J].
Xiao, Lin-Fei ;
Li, Fu-Wei ;
Peng, Ha-Han ;
Xia, Chun-Gu .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 253 (1-2) :265-269
[29]   Zinc polyoxometalate immobilized on ionic liquid-modified MCM-41: an efficient reusable catalyst for the selective oxidation of alcohols with hydrogen peroxide [J].
Robabeh Hajian ;
Fereshteh Jafari .
Journal of the Iranian Chemical Society, 2019, 16 :563-570
[30]   Zinc polyoxometalate immobilized on ionic liquid-modified MCM-41: an efficient reusable catalyst for the selective oxidation of alcohols with hydrogen peroxide [J].
Hajian, Robabeh ;
Jafari, Fereshteh .
JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2019, 16 (03) :563-570
1234