Reaction Kinetics of Carbon Dioxide and Glycidyl Methacrylate using a Ionic Liquid Catalyst of Imidazole Immobilized on MCM41

被引：0
|
作者：
Son, Young-Sik [1 ]
Park, Moon-Ki [2 ]
Kim, Gun-Woo [3 ]
Park, Sang-Wook [1 ]
机构：
[1] Pusan Natl Univ, Div Chem Engn, Busan 609735, South Korea
[2] Daegu Haany Univ, Dept Pharmaceut Engn, 290 Yugok Dong, Gyongsan 712715, Gyeongbuk, South Korea
[3] Small & Medium Business Adm, Busan Ulsan Reg Off, Business Environm Improvement Div, Busan 618819, South Korea
来源：
KOREAN CHEMICAL ENGINEERING RESEARCH | 2009年 / 47卷 / 04期
关键词：
Imidazole; Carbon Dioxide; Absorption; Ionic Liquid;
D O I：
暂无
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Carbon dioxide was absorbed into GMA solution in a stirred flat cell using mesoporous catalyst Imidazole-CP-MS41, which was synthesized by CP-MCM41 with imidazole. Experiments were carried out at a batch-type absorber with different conditions, varying reaction temperature, concentration of GMA, solvent but maintaining 50 rpm of agitation speed and 2 g of catalyst. Absorption rate of CO2 was used to obtain the kinetics based on the film theory using zwitterion mechanism with 2 elementary reaction and the kinetics were correlated with the solubility parameter of the solvents.
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页码：410 / 417
页数：8
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