CHIRAL TETRAPHENYLCYCLOPENTADIENYL COMPLEXES OF RHODIUM - SYNTHESIS AND CRYSTAL-STRUCTURE OF [RH(ETA(5)-C(5)PH(4)CH(ME)PH)(COD)]

被引：5
|
作者：
RAMSDEN, JA
MILNER, D
ADAMS, H
BAILEY, NA
WHITE, C
机构：
[1] UNIV SHEFFIELD,DEPT CHEM,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND
[2] ZENECA SPECIALITIES,MANCHESTER M9 3DA,LANCS,ENGLAND
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 495卷 / 1-2期
关键词：
RHODIUM; TETRAPHENYLCYCLOPENTADIENYL; CHIRALITY; CRYSTAL STRUCTURE; HYDROGENATION; CATALYSIS;
D O I：
10.1016/0022-328X(95)05464-Z
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Phenethyltetraphenylcyclopentadiene has been made from (R)-1-phenethyl bromide (43.8% e.e.) and lithium tetraphenylcyclopentadienide. The syntheses of the hydrogenation catalyst [Rh{C(5)Ph(4)CH(Me)Ph}Br-2](2) and of Rh{C(5)Ph(4)CH(Me)Ph}(C8H12) are also reported along with the crystal structure of the latter.
引用
收藏
页码：215 / 220
页数：6
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