INFLUENCE OF METHOD OF PREPARATION ON AMMONIA-SYNTHESIS ACTIVITY OF CESIUM PROMOTED RUTHENIUM CATALYSTS SUPPORTED ON ACTIVE-CARBON (AC)

被引：0

作者：

MASTHAN, SK ^{[1
]}

RAO, KSR ^{[1
]}

RAO, PK ^{[1
]}

KALUSCHNYAYA, L ^{[1
]}

YUNUSOV, SM ^{[1
]}

SHUR, VB ^{[1
]}

VOLPIN, ME ^{[1
]}

机构：

[1] AN NESMEYANOV ORGANOMET CPDS INST,MOSCOW,RUSSIA

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 1994年 / 33卷 / 09期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cesium promoted ruthenium catalysts supported on active carbon (AC) with the weight ratio of Cs:Ru:AC = 51:10:100 are prepared by three different methods, (1) by depositing CsNO3 on reduced Ru/AC, (2) by simultaneous deposition of CsNO3 and RuCl3 on AC and (3) by depositing RuCl3 on reduced Cs2O/AC through aqueous medium and evaluated for ammonia synthesis at atmospheric pressure and at 400 degrees C. It is observed that the catalyst prepared by method (1) exhibits the highest activity which is almost equal to thermodynamic equilibrium value at 400 degrees C and the activities follow the sequence : catalyst-1 > catalyst-2 much greater than catalyst-3. Ruthenium dispersions of these catalysts are determined by CO chemisorption at ambient temperature. The ammonia synthesis activities of the catalysts are correlated to the dispersion characteristics of ruthenium influenced by the methods of preparation.

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页码：816 / 819

页数：4

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