STEREOCHEMICAL INVESTIGATIONS OF SAMARIUM(II) IODIDE-PROMOTED 5-EXO AND 6-EXO KETYL-OLEFIN RADICAL CYCLIZATION REACTIONS

被引：98
作者：
MOLANDER, GA
MCKIE, JA
机构：
[1] Department of Chemistry, Biochemistry, University of Colorado, Boulder
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1995年 / 60卷 / 04期
关键词：
D O I：
10.1021/jo00109a018
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Samarium(II) iodide (SmI2)-promoted ketyl cyclizations of several substituted, unsaturated ketones, providing various cyclopentyl and cyclohexyl systems, have been investigated. The resulting experiments provide stereochemical insight into these reactions and in addition outline the synthetic potential of these 5-exe and 6-exo radical cyclization processes.
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页码：872 / 882
页数：11
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