NEW ROTATIONAL TRANSITIONS IN (N32S)-N-14-S-32 (X2-PI(3/2))(UPSILON=0,1) DETECTED BY LASER MAGNETIC-RESONANCE AT 561.3-MU-M AND 618.4-MU-M

被引:2
作者
ANACONA, JR
机构
[1] Departamento de Quimica, Universidad de Oriente, Cumanà
来源
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 1995年 / 51卷 / 01期
关键词
D O I
10.1016/0584-8539(94)E0045-C
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
New far infrared laser magnetic resonance (FIR LMR) spectra of N-14-S-32(2II3/2) have been observed at 561.3 and 618.4 mum using DCOOD and C2H3Br optically pumped lasers, respectively. In the first case, the spectrum can be assigned to the rotational transition J = 10.5 --> 11.5 of the ground vibrational state. In the second case, the spectrum can be attributed to the transition J = 9.5 --> 10.5 in the first excited vibrational state. This is the first detection by LMR of N-14S-32 vibrationally excited. The agreement between the theory and experiment confirms the spectroscopic assignments.
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页码:39 / 44
页数:6
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