(Acetylacetonato-kappa O-2,O') bis{5-fluoro-2[3-(4-fluorophenyl) pyrazin-2-yl]phenyl-kappa(2) N-1, C-1} iridium(III)

被引：0

作者：

Ge, Guo-Ping ^{[1
]}

Li, Chun-Yan ^{[1
]}

机构：

[1] Ningbo Univ, Fac Mat Sci & Chem Engn, Inst Solid Mat Chem, State Key Lab Base Novel Funct Mat & Preparat Sci, Ningbo 315211, Zhejiang, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷

关键词：

data-to-parameter ratio = 17.0; mean σ(C-C) = 0.005 Å; R factor = 0.032; single-crystal X-ray study; T = 293 K; wR factor = 0.079;

D O I：

10.1107/S1600536812031546

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title complex, [Ir(C16H9F2N2)(2)(C5H7O2)], the Ir III atom, lying on a twofold rotation axis, is hexacoordinated in a distorted octahedral geometry by two C, N-bidentate 5-fluoro2-[3-(4-fluorophenyl) pyrazin-2-yl] phenyl ligands and one O, O'-bidentate acetylacetonate ligand. The dihedral angles between the benzene rings and the pyrazine ring are 14.66 (8) and 49.76 (12)degrees.

引用

页码：M1079 / +

页数：7

共 7 条

[1] High-efficiency fluorescent organic light-emitting devices using a phosphorescent sensitizer [J].