ELECTROPHILIC REACTIVITY OF ARENE CARBONYL CLUSTER COMPLEXES WITH THE RU6C CORE - CRYSTAL AND MOLECULAR-STRUCTURE OF [RU6C(CO)(14)(ETA(6)-C(6)H(4)PH(2)-1,4)]

被引：10
|
作者：
BORCHERT, T
LEWIS, J
PRITZKOW, H
RAITHBY, PR
WADEPOHL, H
机构：
[1] UNIV CAMBRIDGE,DEPT CHEM,CAMBRIDGE CB2 1EW,ENGLAND
[2] UNIV HEIDELBERG,INST ANORGAN CHEM,D-69120 HEIDELBERG,GERMANY
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1995年 / 06期
关键词：
D O I：
10.1039/dt9950001061
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Addition of LiPh to [Ru6C(CO)(12)(eta(6)-C6H6)(mu-eta(2):eta(2)-C6H8)], [Ru6C(CO)(11)(eta(6)-C6H6)(mu(3)-eta(2):eta(2):eta(2)-C6H6)] and [RU(6)C(CO)(14)(eta(6)-C6H6)], followed by treatment with [CPh(3)][BF4], has led to the substituted arene cluster complexes [RU(6)C(CO)(12)(mu-eta(2):eta(2)-C6H6)(eta(6)-C(6)H(5)Ph)], [Ru6C(CO)(11)(mu(3)-eta(2):eta(2):eta(2)-C6H6)(eta(6)-C(6)H(5)Ph)]and [Ru6C(CO)(14)(eta(6)-C(6)H(4)Ph(2)-1,4)] (structure established by X-ray crystallography).
引用
收藏
页码：1061 / 1062
页数：2
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