Bis[2-(1H-benzimidazol-2-yl)acetato-kappa N-2(3),O] bis(ethanol-kappa O) nickel(II)

被引:0
作者
Wang, Jun [1 ]
Nie, Jian-Hua [1 ]
机构
[1] Zhongshan Polytech, Zhongshan 528404, Guangdong, Peoples R China
关键词
data-to-parameter ratio = 14.7; mean ω(C-C) = 0.006 Å; R factor = 0.049; single-crystal X-ray study; T = 298 K; wR factor = 0.107;
D O I
10.1107/S160053681204514X
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Ni(C9H7N2O2)(2)(C2H5OH)(2)], the Ni-II ion is situated on an inversion center and is coordinated by two N and two O atoms from two 2-(1H-benzimidazol- 2-yl) acetate (L) ligands and by two O atoms from two ethanol ligands in a distorted octahedral geometry. In the L ligand, the acetate group deviates significantly from the benzimidazole plane, the C-C-C-O(coordinating) torsion angle being 34.2 (5)degrees. In the crystal, O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds link the molecules into a two- dimensional supramolecular network parallel to the bc plane.
引用
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页码:M1461 / +
页数:8
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