HYDRODECHLORINATION OF CHLOROAROMATICS - THE USE OF A BIFUNCTIONAL HOMOGENOUS RHODIUM CATALYST FOR THE CONVERSION OF CHLOROAROMATICS INTO SATURATED-HYDROCARBONS

被引：40

作者：

FERRUGHELLI, DT ^{[1
]}

HORVATH, IT ^{[1
]}

机构：

[1] EXXON RES & ENGN CO,CORP RES LABS,ANNANDALE,NJ 08801

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 11期

关键词：

D O I：

10.1039/c39920000806

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The catalytic conversion of chloroaromatics into the corresponding saturated hydrocarbons is catalysed by a bifunctional homogeneous rhodium catalyst system generated from [(C5Me5)RhCl2]2 in the presence of an excess of NEt3 under 600 psi H-2 at 75-degrees-C (1 psi almost-equal-to 6.894757 x 10(3) Pa).

引用

页码：806 / 807

页数：2

共 6 条

[1]

ACKERMAN DG, 1983, DESTRUCTION DISPOSAL

[2]

BENNETT M, 1980, CHEMTECH, P444

[3]

FISH RH, 1990, ASPECTS HOMOGENEOUS, V7, P65

[4] RHODIUM(III) BIPHASIC AND PHASE-TRANSFER-CATALYZED HYDROGENOLYSIS OF CHLOROARENES UNDER EXCEPTIONALLY MILD CONDITIONS [J].

GRUSHIN, VV ;

ALPER, H .

ORGANOMETALLICS, 1991, 10 (05) :1620-1622

[5]

HUTZINGER O, 1974, CHEM PCBS

[6] (PENTAMETHYLCYCLOPENTADIENYL)RHODIUM AND (PENTAMETHYLCYCLOPENTADIENYL)IRIDIUM COMPLEXES - APPROACHES TO NEW TYPES OF HOMOGENEOUS CATALYSTS [J].

MAITLIS, PM .

ACCOUNTS OF CHEMICAL RESEARCH, 1978, 11 (08) :301-307

← 1 →