HELICAL AMYLOSE COMPLEXES WITH ORGANIC-COMPOUNDS .2. CIRCULAR-DICHROISM AND ULTRAVIOLET SPECTROSCOPY OF COMPLEXES OF AMYLOSE

被引:37
作者
WULFF, G
KUBIK, S
机构
[1] Institut für Organische Chemie und Makromolekulare Chemie, Heinrich-Heine Universität Düsseldorf, 4000 Düsseldorf
关键词
D O I
10.1016/S0008-6215(92)84228-K
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The circular dichroism of the complexes formed between slightly hydroxypropylated amylose and cyclomalto-hexaose, -heptaose, and -octaose (alpha-, beta-, and gamma-cyclodextrin) with nine different achiral ketones and phenolphthalein has been investigated. In the complexes with the ketones, the amylose helix has a conformation with six glucose units per turn, whereas, in the complex with phenolphthalein, it has seven.
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页码:1 / 10
页数:10
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