Half-Sandwich Ruthenium Complexes of Heterocyclic-Dithiocarboxylato Ligands

被引:0
|
作者
El-Khateeb, Mohammad [1 ]
Al-Noaimi, Mousa [2 ]
Harb, Mohammad [3 ]
Goerls, Helmar [3 ]
Weigand, Wolfgang [3 ]
机构
[1] Jordan Univ Sci & Technol, Chem Dept, Irbid 22110, Jordan
[2] Hashemite Univ, Chem Dept, Zarqa, Jordan
[3] Friedrich Schiller Univ Jena, Inst Anorgan Chem, D-07743 Jena, Germany
关键词
Complexes; Ruthenium; Dithiocarboxylate; Structure; Sulfur; Heterocycles;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The heterocyclic-dithiocarboxylato complexes CpRu(PPh3)(kappa S-2, S-S2C-het) [het= 2-C4H3O (1), 2-C4H3S (2), 1-C4H8N (3)] are obtained by the reaction of the ruthenium chloride, CpRu(PPh3)(2)Cl, with the anions, het-CS2-. The X-ray structure of CpRu(PPh3)(kappa S-2, S-S2C-1-C4H8N) (3) is determined by single crystal X-ray diffraction.
引用
收藏
页码:147 / 153
页数:7
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