PEROXIDE ROUTE TO PENTAOXYPHOSPHORANES

被引：79

作者：

DENNEY, DB

JONES, DH

机构：

[1] School of Chemistry, Rutgers University, New Brunswick

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 21期

关键词：

D O I：

10.1021/ja01049a020

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A variety of pentaoxyphosphoranes have been prepared by allowing trisubstituted phosphites to react with diethyl peroxide. In one case the same pentaoxyphosphorane was prepared by condensation of β-naphthoquinone and triethyl phoshite and by reaction of the phosphite, 3, with diethyl peroxide. The relative rates of formation of the pentaoxyphosphoranes have been obtained as a function of structure. Decomposition of five-membered ring containing pentaoxyphosphoranes gives epoxides in a stereospecific process. © 1969, American Chemical Society. All rights reserved.

引用

页码：5821 / &

共 27 条

[1] RATE STUDIES OF MICHAELIS-ARBUZOV REACTION BETWEEN ETHYL IODIDE AND CYCLIC PHOSPHITES [J].