INELASTIC NEUTRON-SCATTERING STUDY OF THE METAL CLUSTER COMPOUND LI6[ZR6CL1H]

被引：7

作者：

CORBETT, JD

ECKERT, J

JAYASOORIYA, UA

KEARLEY, GJ

WHITE, RP

ZHANG, J

机构：

[1] UNIV E ANGLIA,SCH CHEM SCI,NORWICH NR4 7TJ,NORFOLK,ENGLAND

[2] IOWA STATE UNIV SCI & TECHNOL,DEPT CHEM,AMES,IA 50011

[3] INST MAX VON LAUE PAUL LANGEVIN,F-38042 GRENOBLE,FRANCE

[4] LOS ALAMOS NATL LAB,LOS ALAMOS,NM 87545

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1993年 / 97卷 / 32期

关键词：

D O I：

10.1021/j100134a004

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The optic modes of the hydrogen in the metal cluster compound Li6[Zr6Cl18H] are observed at 480 and 790 cm-1 using incoherent inelastic neutron scattering spectroscopy at approximately 15 K, and confirmed using the spectrum of the deuterium substituted compound. This observation is rationalized in terms of a model with the hydrogen occupying a mu3-bridging position within the octahedral interstitial site with a Zr-H bond distance of ca. 2.0 angstrom. The terminal and bridge bonded chlorine vibrations are observed at frequencies of approximately 280 and approximately 190 cm-1, respectively.

引用

收藏

页码：8384 / 8386

页数：3

相关论文

共 18 条

[1] METAL-HYDROGEN STRETCHING FREQUENCIES FROM MU-3-BRIDGED METAL HYDRIDE CLUSTER COMPLEXES AND HYDROGEN ADSORBED ON METAL-SURFACES [J].

ANDREWS, JA ;

JAYASOORIYA, UA ;

OXTON, IA ;

POWELL, DB ;

SHEPPARD, N ;

JACKSON, PF ;

JOHNSON, BFG ;

LEWIS, J .

INORGANIC CHEMISTRY, 1980, 19 (10) :3033-3036

[2]

ANSON CE, 1980, J INORG CHEM, V19, P3033

[3] NMR-STUDIES OF THE MOTION OF THE HYDRIDE PROTON IN SOLID HRU10C(CO)24- [J].

BAILEY, PJ ;

DUER, MJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (16) :1139-1141

[4]

BROACH RW, 1978, ADV CHEM SER, V167, P93

[5] CHARACTERIZATION OF INTERSTITIAL HYDROGEN WITHIN METAL-CLUSTERS IN ZR6CL12H AND ZRCLOXHY BY SOLID-STATE NUCLEAR MAGNETIC-RESONANCE [J].

CHU, PJ ;

ZIEBARTH, RP ;

CORBETT, JD ;

GERSTEIN, BC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (16) :5324-5329

[6] TEMPERATURE AND CONCENTRATION-DEPENDENCE OF HYDROGEN SITE OCCUPANCY IN SEVERAL RARE-EARTH DIHYDRIDES [J].

GOLDSTONE, JA ;

ECKERT, J ;

RICHARDS, PM ;

VENTURINI, EL .

PHYSICA B & C, 1986, 136 (1-3) :183-186

[7] INCOHERENT INELASTIC NEUTRON-SCATTERING STUDIES OF TRANSITION-METAL HYDRIDOCARBONYLS .1. CS+[HCO6(CO)15]- [J].

GRAHAM, D ;

HOWARD, J ;

WADDINGTON, TC ;

TOMKINSON, J .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1983, 79 :1713-1717

[8] AN INTERSTITIAL HYDROGEN-ATOM IN A HEXANUCLEAR METAL CLUSTER - X-RAY AND NEUTRON-DIFFRACTION ANALYSIS OF [(PH3P)2N]+[HCO6(CO)15]- [J].

HART, DW ;

TELLER, RG ;

WEI, CY ;

BAU, R ;

LONGONI, G ;

CAMPANELLA, S ;

CHINI, P ;

KOETZLE, TF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (06) :1458-1466

[9] 6-COORDINATE HYDROGEN - STRUCTURE OF [PH3P)2N]+[HC06(CO)15] BY SINGLE-CRYSTAL NEUTRON-DIFFRACTION ANALYSIS [J].

HART, DW ;

TELLER, RG ;

WEI, CY ;

BAU, R ;

LONGONI, G ;

CAMPANELLA, S ;

CHINI, P ;

KOETZLE, TF .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1979, 18 (01) :80-81

[10] A PROFILE-REFINEMENT APPROACH FOR NORMAL-COORDINATE ANALYSES OF INELASTIC NEUTRON-SCATTERING SPECTRA [J].

KEARLEY, GJ .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1986, 82 :41-48