VOLTAMMETRY OF MOLECULAR FILMS CONTAINING ACID-BASE GROUPS

被引：196

作者：

SMITH, CP ^{[1
]}

WHITE, HS ^{[1
]}

机构：

[1] UNIV MINNESOTA,DEPT CHEM ENGN & MAT SCI,MINNEAPOLIS,MN 55455

来源：

LANGMUIR | 1993年 / 9卷 / 01期

关键词：

Coated metal electrodes - Molecular films - Monolayer - Voltammetry;

D O I：

10.1021/la00025a001

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The differential capacitance of metal electrodes coated with monolayer films of a molecular acid or base is shown to be a function of the applied potential and solution pH. Maxima and minims are predicted to occur in the voltammetric (i-E) response to these electrodes, providing a theoretical basis for quantitative electroanalyses of acid-base surface chemistry.

引用

页码：1 / 3

页数：3

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