A PRACTICAL, HIGHLY STEREOSELECTIVE SYNTHESIS OF THE TRISACCHARIDE REPEATING UNIT OF A STREPTOCOCCUS-PNEUMONIAE POLYSACCHARIDE

被引：12

作者：

KAJI, E ^{[1
]}

LICHTENTHALER, FW ^{[1
]}

OSA, Y ^{[1
]}

TAKAHASHI, K ^{[1
]}

MATSUI, E ^{[1
]}

ZEN, S ^{[1
]}

机构：

[1] TH DARMSTADT, INST ORGAN CHEM, W-6100 DARMSTADT, GERMANY

来源：

CHEMISTRY LETTERS | 1992年 / 05期

关键词：

D O I：

10.1246/cl.1992.707

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A highly stereoselective method has been developed for the synthesis of the trisaccharide component of the capsular polysaccharide of Streptococcus pneumoniae type 19F. The key intermediate, 2-benzoyloxyiminoglycosyl bromide was successfully utilized for the construction of the N-acetyl-beta-D-mannosamine unit of the trisaccharide.

引用

页码：707 / 710

页数：4

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