ENANTIOCONTROLLED SYNTHESES OF THE CUPARENE SESQUITERPENES, (-)-HERBERTENE, (+)-BETA-CUPARENONE, (-)-DEBROMOAPLYSIN, AND (-)-APLYSIN

被引：52

作者：

TAKANO, S

MORIYA, M

OGASAWARA, K

机构：

[1] Pharmaceutical Institute, Tohoku University, Sendai, 980, Aobayama

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 03期

关键词：

D O I：

10.1016/S0040-4039(00)74123-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Enantiocontrolled syntheses of the Cuparene sesquiterpenes, (-)-herbertene, (+)-beta-cuparenone, (-)-debromoaplysin, and (-)-aplysin, have been achieved starting from the optically active tricyclic dienone by employing a Fischer indolization reaction under non-acidic conditions as the key step.

引用

页码：329 / 332

页数：4

共 24 条

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