REACTIONS OF PHENOXIDE ION IN THE GAS-PHASE

被引：11
|
作者：
BINKLEY, RW [1 ]
TEVESZ, MJS [1 ]
WINNIK, W [1 ]
机构：
[1] CLEVELAND STATE UNIV,DEPT GEOL SCI,CLEVELAND,OH 44115
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1992年 / 57卷 / 20期
关键词：
D O I：
10.1021/jo00046a037
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Upon collisionally activated dissociation (CAD) phenoxide ion experiences fragmentation reactions in the gas phase that produce the daughter ions [C6H3]-, [C5H5]-, [C2HO]-, and [C3H3]-. Based upon study of the anions derived from 2,3,4,5,6-pentadeuteriophenol (2), 4-deuteriophenol (3), 3,5-dideuteriophenol (4), and 2,4,6-trideuteriophenol (5), mechanisms for formation of the [C6H3]-, [C5H5]-, and [C2HO]- ions have been proposed.
引用
收藏
页码：5507 / 5509
页数：3
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