STUDY ON THE GEOMETRIC STRUCTURE OF POLY[1-(TRIMETHYLSILYL)-1-PROPYNE] BY C-13 AND SI-29 NMR SPECTROSCOPIES

被引：27

作者：

IZUMIKAWA, H

MASUDA, T

HIGASHIMURA, T

机构：

[1] Department of Polymer Chemistry, Kyoto University, Kyoto

来源：

POLYMER BULLETIN | 1991年 / 27卷 / 02期

关键词：

D O I：

10.1007/BF00296030

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The geometric structure of poly[1-(trimethylsilyl)-1-propyne] was investigated by C-13 and Si-29 NMR spectroscopies. According to C-13 NMR, the geometric structure varied with polymerization catalysts. NbCl5 was inferred to produce more cis-rich polymer than TaCl5. On the other hand, polymerization conditions such as solvent, temperature and cocatalyst hardly affected the geometric structure. The cis contents of polymers bearing bulkier substituents (-SiMe2-nC6H13, -SiMe2-CH2SiMe3) prepared with TaCl5 were similar to that of poly(TMSP) with TaCl5.

引用

收藏

页码：193 / 199

页数：7

相关论文

共 10 条

[1] A STUDY BY SOLID-STATE AND SOLUTION C-13 NMR ON SILICON-CONTAINING POLYACETYLENES [J].

COSTA, G ;

GROSSO, A ;

SACCHI, MC ;

STEIN, PC ;

ZETTA, L .

MACROMOLECULES, 1991, 24 (10) :2858-2861

[2] POLYMERIZATION OF HETEROATOM CONTAINING ACETYLENES .6. POLYMERIZATION OF 1-(TRIMETHYLSILYL)-1-PROPYNE HOMOLOGS CONTAINING 2 SILICON ATOMS BY TANTALUM-BASED AND NIOBIUM-BASED CATALYSTS [J].

ISOBE, E ;

MASUDA, T ;

HIGASHIMURA, T ;

YAMAMOTO, A .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1986, 24 (08) :1839-1848

[3] SIMULTANEOUS POLYMERIZATION AND FORMATION OF POLYACETYLENE FILM ON SURFACE OF CONCENTRATED SOLUBLE ZIEGLER-TYPE CATALYST SOLUTION [J].

ITO, T ;

SHIRAKAWA, H ;

IKEDA, S .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1974, 12 (01) :11-20

[4]

IZUMIKAWA H, 1990, POLYM PREP JPN ENGL, V39, pE99

[5] POLYMERIZATIONS OF ACETYLENES AND CYCLIC OLEFINS INDUCED BY METAL CARBYNES [J].

KATZ, TJ ;

HO, TH ;

SHIH, NY ;

YING, YC ;

STUART, VIW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (09) :2659-2668

[6] POLYMERIZATION OF SILICON-CONTAINING ACETYLENES .4. SYNTHESIS OF POLY[1-(TRIMETHYLSILYL)-1-PROPYNE] WITH EXTREMELY HIGH-MOLECULAR-WEIGHT BY USING TACL5-PH3BI (1-1) CATALYST [J].

MASUDA, T ;

ISOBE, E ;

HAMANO, T ;

HIGASHIMURA, T .

MACROMOLECULES, 1986, 19 (09) :2448-2450

[7] POLYMERIZATION OF 1-(TRIMETHYLSILYL)-1-PROPYNE BY HALIDES OF NIOBIUM(V) AND TANTALUM(V) AND POLYMER PROPERTIES [J].

MASUDA, T ;

ISOBE, E ;

HIGASHIMURA, T .

MACROMOLECULES, 1985, 18 (05) :841-845

[8] POLYMERIZATION OF SILICON-CONTAINING ACETYLENES .5. POLYMERIZATION OF 1-SILYL-1-PROPYNES BY TACL5-BASED CATALYSTS [J].

MASUDA, T ;

ISOBE, E ;

HAMANO, T ;

HIGASHIMURA, T .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1987, 25 (05) :1353-1362

[9] CHAIN TRANSFER-REACTION BY TRIMETHYLVINYLSILANE IN THE POLYMERIZATION OF SUBSTITUTED ACETYLENES [J].

MASUDA, T ;

KOUZAI, H ;

HIGASHIMURA, T .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (04) :252-253

[10] POLYMERIZATION OF ALIPHATIC ACETYLENES .5. POLYMERIZATION OF TERT-BUTYLACETYLENE BY GROUP-6 TRANSITION-METAL CATALYSTS - GEOMETRIC STRUCTURE CONTROL BY REACTION CONDITIONS [J].

OKANO, Y ;

MASUDA, T ;

HIGASHIMURA, T .

POLYMER JOURNAL, 1982, 14 (06) :477-483