THERMOPHYSICAL PROPERTIES OF ALKANES FROM SPEEDS OF SOUND DETERMINED USING A SPHERICAL RESONATOR .4. 2-METHYLPROPANE AT TEMPERATURES IN THE RANGE 251-K TO 320-K AND PRESSURES IN THE RANGE 5 KPA TO 114 KPA

被引:28
作者
EWING, MB [1 ]
GOODWIN, ARH [1 ]
机构
[1] UNIV LONDON UNIV COLL,DEPT CHEM,LONDON WC1H 0AJ,ENGLAND
关键词
D O I
10.1016/S0021-9614(05)80141-7
中图分类号
O414.1 [热力学];
学科分类号
摘要
The speeds of sound in gaseous 2-methylpropane have been obtained at temperatures between 251 K and 320 K from measurements of the frequencies of the radial acoustic modes of a spherical cavity. Perfect-gas heat capacities and second and third acoustic virial coefficients have been determined from the results. Second and third coefficients of the virial equation of state have been calculated from the acoustic virial coefficients. We also report vibrational relaxation times for 2-methylpropane. © 1991 Academic Press Limited All rights reserved.
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页码:1107 / 1120
页数:14
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