POLAROGRAPHIC INVESTIGATION OF POLYMERIZATION OF UNSATURATED KETONES .1. ACID CATALYZED POLYMERIZATION OF METHYL VINYL KETONE IN METHANOLIC SOLUTION

被引：7

作者：

HOLLECK, L

MAHAPATR.S

机构：

来源：

MONATSHEFTE FUR CHEMIE | 1969年 / 100卷 / 06期

关键词：

D O I：

10.1007/BF01151743

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Polarographic curves of conjugated unsaturated ketones - in the present case methylvinylketone (MVK) - in acid solutions change with time due to polymerization. The effect of proton donors (strong and weak acids) to methanolic solutions of MVK on the shape and position as well as on the rate of decrease of the wave height allow to formulate the polymerization-mechanism (initiation-, propagation-and termination-reaction). The polarographic method proves to be suitable to observe and clarify polymerization reactions, if the monomer species show reduction-waves. © 1969 Springer-Verlag.

引用

页码：1928 / &

共 13 条

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