SYNTHESIS OF 5-EPI-ARIZONIN-B1 AND 5-EPI-ARIZONIN-C1

被引:23
作者
BRIMBLE, MA [1 ]
PHYTHIAN, SJ [1 ]
机构
[1] MASSEY UNIV,DEPT CHEM & BIOCHEM,PALMERSTON NORTH,NEW ZEALAND
关键词
D O I
10.1016/S0040-4039(00)73868-8
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The first synthesis of 5-epi-arizonin B1 (19) and 5-epi-arizonin C1 (18) is described in which the key step involves rearrangement of a furo[3,2-b]naphtho[2,1-d]furan (16) to a furo[3,2-b]naphtho[2,3-b]naphtho[2,3-d]pyran (17). Regioselective synthesis of naphthoquinone (15) was crucial to this synthetic strategy.
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页码:5813 / 5814
页数:2
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