EPR RECORDING OF FATTY AROMATIC RADICALS DURING CHLORARYLATION

被引：0

作者：

LYAKHOVICH, MB ^{[1
]}

GASANOV, RG ^{[1
]}

OBUSHAK, ND ^{[1
]}

GANUSHCHAK, NI ^{[1
]}

TODRES, ZV ^{[1
]}

机构：

[1] I FRANKO STATE TEACHERS INST,LVOV,UKRAINE,USSR

来源：

BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE | 1991年 / 40卷 / 05期

关键词：

D O I：

10.1007/BF00961385

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of aryldiazonium chlorides with unsaturated compounds in the presence of copper dichloride leads to chlorarylation products having a multiple bond. In the initial stage an aryldiazonium salt is formed with a complex tetrachlorocuprate anion (ArN2)2 2+CuCl4(2-). This salt reacts with styrene or acrylonitrile to give radicals of the type ArCH2CHX (Ar = p-MeOC6H4, X = Ph, CN), which were recorded from the corresponding EPR spectra in the form of spin adducts of nitrosodurol.

引用

页码：1093 / 1094

页数：2