SYNTHESIS AND PROPERTIES OF MANGANESE HYDRIDES HAVING A FUNCTIONAL SILICON

被引：55

作者：

COLOMER, E ^{[1
]}

CORRIU, RJP ^{[1
]}

VIOUX, A ^{[1
]}

机构：

[1] UNIV MONTPELLIER 2,CNRS,ORGANOMET LAB,EQUIPE RECH 554,F-34060 MONTPELLIER,FRANCE

来源：

INORGANIC CHEMISTRY | 1979年 / 18卷 / 03期

关键词：

D O I：

10.1021/ic50193a033

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complexes of the type (η5-CH3C5H4)(CO)2Mn(H)SiR1R2X where R1=phenyl, R2=1-naphthyl, and X=hydrogen, chlorine, fluorine, or methoxy have been prepared, and their chemical behavior has been studied. The different types of reactions they undergo are the following: (i) deinsertion reactions with formation of R1R2Si(H)X, (ii) cleavage of the Mn-Si bond with water or methanol, (iii) substitution reactions at silicon without cleavage of the Mn-Si bond, (iv) formation of salts by abstraction of H+, and (v) reaction with LiAlH4, which leads first to reduction of the function X and then to formation of the anion [(η-CH3CsH4(CO)2MnSiR1H2]-. © 1979, American Chemical Society. All rights reserved.

引用

页码：695 / 700

页数：6

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