A FACILE GENERAL-METHOD FOR THE PREPARATION OF S-METHYL THIOLCARBAMATES USING ZEOLITE CATALYSTS

被引：20

作者：

REDDY, TI ^{[1
]}

BHAWAL, BM ^{[1
]}

RAJAPPA, S ^{[1
]}

机构：

[1] NATL CHEM LAB,DIV ORGAN CHEM SYNTH,POONA 411008,MAHARASHTRA,INDIA

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 20期

关键词：

D O I：

10.1016/S0040-4039(00)78879-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Dimethyl carbonimidodithioates derived from various primary amines and amino acid esters (1) can be converted to S-methyl thiolcarbamates (2) by H-mordenite or H-Y zeolite catalysis in moderate to good yields.

引用

页码：2857 / 2860

页数：4

共 11 条

[1]

ANLEY AD, 1944, J CHEM SOC, P147

[2]

Breck D. W, 1974, ZEOLITE MOL SIEVES

[3]

Chin-Hsien W., 1981, SYNTHESIS-STUTTGART, P622

[4]

DESHMUKH ARA, 1990, J CHEM SOC P1, P1227

[5]

HOPPE D, 1979, LIEBIGS ANN CHEM, P2066

[6] MECHANISM OF ACID-CATALYZED REARRANGEMENT OF THIONOCARBAMATES [J].

KINOSHIT.Y ;

MISAKA, M ;

ISHIKAWA, H ;

KUBOTA, S .

AGRICULTURAL AND BIOLOGICAL CHEMISTRY, 1972, 36 (11) :1975-&

[7]

Kinoshita Y., 1966, AGR BIOL CHEM TOKYO, V30, P710

[8] FACILE SYNTHESIS OF S-ALKYL THIOCARBAMATES THROUGH REACTION OF CARBAMOYL LITHIUM WITH ELEMENTAL SULFUR [J].

MIZUNO, T ;

NISHIGUCHI, I ;

OKUSHI, T ;

HIRASHIMA, T .

TETRAHEDRON LETTERS, 1991, 32 (47) :6867-6868

[9] SELENIUM-CATALYZED SYNTHESIS OF S-ALKYL THIOCARBAMATES FROM AMINES, CARBON-MONOXIDE, SULFUR, AND ALKYL-HALIDES [J].

SONODA, N ;

MIZUNO, T ;

MURAKAMI, S ;

KONDO, K ;

OGAWA, A ;

RYU, I ;

KAMBE, N .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (04) :452-453

[10]

Szostak R., 1989, MOL SIEVES PRINCIPLE

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