DIRECT FORMATION OF FORMIC-ACID FROM CARBON-DIOXIDE AND DIHYDROGEN USING THE [(RH(COD)CL)2]-PH2P(CH2)4PPH2 CATALYST SYSTEM

被引：155

作者：

GRAF, E ^{[1
]}

LEITNER, W ^{[1
]}

机构：

[1] UNIV REGENSBURG,INST ANORGAN CHEM,UNIV STR 31,W-8400 REGENSBURG,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 08期

关键词：

D O I：

10.1039/c39920000623

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Formic acid, isolable as sodium formate from the reaction mixture, is produced directly from hydrogen and carbon dioxide with yields up to 1150 moles per mole of rhodium using a homogeneous catalyst formed in situ from [{Rh(cod)Cl}2] and Ph2P(CH2)4PPh2; the precious metal is recovered during work-up in a catalytically active form.

引用

页码：623 / 624

页数：2

共 13 条

[1] CARBON-DIOXIDE AS AN ALTERNATIVE C1 SYNTHETIC UNIT - ACTIVATION BY TRANSITION-METAL COMPLEXES [J].

BEHR, A .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (05) :661-678

[2]

Behr A., 1988, CARBON DIOXIDE ACTIV

[3] REACTIONS OF CARBON-DIOXIDE WITH CARBON CARBON BOND FORMATION CATALYZED BY TRANSITION-METAL COMPLEXES [J].

BRAUNSTEIN, P ;

MATT, D ;

NOBEL, D .

CHEMICAL REVIEWS, 1988, 88 (05) :747-764

[4] ASYMMETRIC CATALYSIS .52. RHODIUM CATALYZED ENANTIOSELECTIVE TRANSFER HYDRATION OF C=C DOUBLE-BONDS WITH THE HCO2H/NET3 SYSTEM AS A HYDROGEN SOURCE [J].

BRUNNER, H ;

LEITNER, W .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 387 (02) :209-217

[5] ENANTIOSELECTIVE CATALYSIS .43. ENANTIOSELECTIVE CATALYTIC TRANSFER-HYDROGENATION OF ALPHA,BETA-UNSATURATED CARBOXYLIC-ACIDS WITH TRIETHYLAMMONIUM FORMATE [J].

BRUNNER, H ;

LEITNER, W .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1988, 27 (09) :1180-1181

[6]

BRUNNER H, 1989, SYNTHESIS-STUTTGART, P743

[7]

HAYNES P, 1970, TETRAHEDRON LETT, P365

[8] CATALYTIC FIXATION OF CARBON-DIOXIDE TO FORMIC-ACID BY TRANSITION-METAL COMPLEXES UNDER MILD CONDITIONS [J].

INOUE, Y ;

IZUMIDA, H ;

SASAKI, Y ;

HASHIMOTO, H .

CHEMISTRY LETTERS, 1976, (08) :863-864

[9] SYNTHESIS OF FORMATES FROM ALCOHOLS, CARBON-DIOXIDE, AND HYDROGEN CATALYZED BY A COMBINATION OF GROUP-8 TRANSITION-METAL COMPLEXES AND TERTIARY-AMINES [J].

INOUE, Y ;

SASAKI, Y ;

HASHIMOTO, H .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1975, (17) :718-719

[10]

NARITA K, 1977, CHEM PHARM BULL, V25, P135

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