Ion-Pair Formation in Aqueous Solutions of Silver Nitrate: A Raman and Infrared Spectral Study

被引：0

作者：

Chang, Tien-chung Godfrey ^{[1
]}

Irish, Donald E. ^{[1
]}

机构：

[1] Univ Waterloo, Dept Chem, Waterloo, ON N2L 3G1, Canada

来源：

JOURNAL OF SOLUTION CHEMISTRY | 1974年 / 3卷 / 03期

关键词：

Silver nitrate; Raman spectroscopy; ion pair; infrared spectroscopy;

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A detailed study of the Raman and infrared spectral line shapes and line parameters of aqueous solutions (both H2O and D2O) of AgNO3 is interpreted in terms of an equilibrium between "'free" ions and the ion pair Ag+NO3-. An association constant of 0.1 M-1 was obtained from both the 717 cm(-1) and 1047 cm(-1) line intensities. Spectral features suggest a significant degree of covalence in the interaction. A C-s(sigma(V)) model with Ag+ above the plane of NO3- is consistent with the data.

引用

页码：175 / 189

页数：15

共 50 条

[1] Ion-pair formation of hydroquinine by chromatography
Marchais, S
Vermeulen, ES
Semple, G
Sundell, S
Wikström, HV
ANALYTICA CHIMICA ACTA, 2001, 426 (01) : 85 - 93
[2] Experimental and quantum mechanical studies on the ion-pair of levocetirizine and bromocresol green in aqueous solutions
Dena, Ahmed S. Abo
Hassan, Walid M. I.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2016, 163 : 108 - 114
[3] Ion-pair and triple-ion formation in low permittivity solvent: a conductometric study
Dewan, Rajani
Roy, Mahendra Nath
PHYSICS AND CHEMISTRY OF LIQUIDS, 2011, 49 (02) : 145 - 154
[4] RAMAN SPECTRAL STUDY OF IONIC HYDRATION IN AQUEOUS PERCHLORATE SOLUTIONS
JEREMIC, M
ANTICJOVANOVIC, A
LALIC, M
BOJOVIC, V
SPECTROSCOPY LETTERS, 1992, 25 (01) : 55 - 61
[5] Hydrogen-Bonding-Driven Ion-Pair Formation in Protic Ionic Liquid Aqueous Solution
Zhang, Lei
Zhang, Zhang
Yuan, Wen-Li
Zhao, Nanrong
Zhu, Qiu-Hong
He, Ling
Tao, Guo-Hong
CHEMPHYSCHEM, 2019, 20 (23) : 3259 - 3268
[6] Characterization of aqueous silver nitrate solutions for leakage tests
Costa, Jose Ferreira
Siqueira, Walter Luiz
Loguercio, Alessandro Dourado
Reis, Alessandra
de Oliveira, Elizabeth
Coelho Alves, Claudia Maria
de Oliveira Bauer, Jose Roberto
Miranda Grande, Rosa Helena
JOURNAL OF APPLIED ORAL SCIENCE, 2011, 19 (03) : 254 - 259
[7] A new model in correlating the activity coefficients of aqueous electrolyte solutions with ion pair formation
Mortazavi-Manesh, Sepideh
Taghikhani, Vahid
Ghotbi, Cyrus
FLUID PHASE EQUILIBRIA, 2007, 261 (1-2) : 313 - 319
[8] RAMAN SPECTRAL STUDIES OF AQUEOUS ACIDIC PYRAZINE SOLUTIONS
BROLO, AG
IRISH, DE
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, 1995, 50 (2-3): : 274 - 282
[9] Volume Change of Ion Pair Formation: Rubidium Nitrate and Thallium(I) Nitrate in Water
Masterton, William L.
Welles, Harry
Knox, Jonathan H.
Millero, Frank J.
JOURNAL OF SOLUTION CHEMISTRY, 1974, 3 (02) : 91 - 102
[10] Solvation and Ion Association in the System AgNO3-CH3CN: A Raman and Infrared Spectral Study
Chang, Tien-chung Godfrey
Irish, Donald E.
JOURNAL OF SOLUTION CHEMISTRY, 1974, 3 (03) : 161 - 174

← 1 2 3 4 5 →