INTRAMOLECULAR TRANSFER OF CO FROM (ETA(6)-ARENE)CR(CO)(3) COMPLEXES IN STILLE-TYPE PALLADIUM-CATALYZED CROSS-COUPLING REACTIONS

被引：25

作者：

CALDIROLA, P ^{[1
]}

CHOWDHURY, R ^{[1
]}

JOHANSSON, AM ^{[1
]}

HACKSELL, U ^{[1
]}

机构：

[1] UNIV UPPSALA,CTR BIOMED,S-75123 UPPSALA,SWEDEN

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 08期

关键词：

D O I：

10.1021/om00008a041

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Arylketones were formed from the Cr(CO)(3) complex of (trialkylstannyl)benzene or chlorobenzene by a palladium-catalyzed cross-coupling reaction in the absence of external CO. The Cr(CO)(3) moiety provides the required CO predominantly by an intramolecular mechanism. Products due to a direct coupling reaction were also observed. The influence of solvent, temperature, substrate, and catalyst on the relative amount of products due to both carbonylative coupling and direct coupling were studied.

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页码：3897 / 3900

页数：4

相关论文

共 48 条

[1]

[Anonymous], 1979, INORG SYNTH

[2] SUNLAMP-IRRADIATED PHASE-TRANSFER CATALYSIS .1. COBALT CARBONYL CATALYZED SRN1 CARBONYLATIONS OF ARYL AND VINYL HALIDES [J].

BRUNET, JJ ;

SIDOT, C ;

CAUBERE, P .

JOURNAL OF ORGANIC CHEMISTRY, 1983, 48 (08) :1166-1171

[3]

CARPENTIER JF, 1993, J MOL CATAL, V8, P1

[4]

CAVALLO AS, 1985, POLYHEDRON, V4, P901

[5] REACTIONS OF PALLADIUM(II) WITH ORGANIC COMPOUNDS .3. REACTIONS OF AROMATIC IODIDES IN BASIC-MEDIA [J].

CLARK, FRS ;

NORMAN, ROC ;

THOMAS, CB .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1975, (02) :121-125

[6] SELECTIVE SYNTHESES OF ALIPHATIC KETONES USING SODIUM TETRACARBONYLFERRATE(-II) [J].

COLLMAN, JP ;

CLARK, DR ;

WINTER, SR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (05) :1788-&

[7] BASE-CATALYZED CARBOXYLATION OF ORGANIC HALIDES NICKEL CARBONYL IN PROTIC MEDIA [J].

COREY, EJ ;

HEGEDUS, LS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (05) :1233-&

[8] BIMETALLIC ACTIVATION IN HOMOGENEOUS CATALYSIS .2. FORMATION OF ALPHA-OXO AMIDE BY PALLADIUM-CATALYZED DOUBLE CARBONYLATION OF THE TRICARBONYL (CHLOROBENZENE) CHROMIUM COMPLEX [J].

DANY, F ;

MUTIN, R ;

LUCAS, C ;

DUFAUD, V ;

THIVOLLECAZAT, J ;

BASSET, JM .

JOURNAL OF MOLECULAR CATALYSIS, 1989, 51 (02) :L15-L20

[9]

DAVIES JA, 1981, CHEM REV, P79

[10] BIMETALLIC ACTIVATION IN HOMOGENEOUS CATALYSIS .3. MECHANISTIC STUDY OF THE METHOXYCARBONYLATION OF TRICARBONYL(CHLOROBENZENE)CHROMIUM - ISOLATION AND REACTIVITY OF POSSIBLE REACTION INTERMEDIATES [J].

DUFAUD, V ;

THIVOLLECAZAT, J ;

BASSET, JM ;

MATHIEU, R ;

JAUD, J ;

WAISSERMANN, J .

ORGANOMETALLICS, 1991, 10 (12) :4005-4015

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