Crystal structure of bis{N-[(diethylamino)dimethylsilyl]anilido-kappa N-2,N'}-zinc

被引：0
作者：
Chen, Juan [1 ]
机构：
[1] Taiyuan Teachers Coll, Dept Chem, Taiyuan 030031, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷
关键词：
crystal structure; zinc amide; N-donor; N-Si-N chelating ligand;
D O I：
10.1107/S2056989015022768
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title zinc amide, [Zn(C12H21N2Si)(2)], was prepared by the metathetical reaction of [LiN(SiMe2NEt2)(C6H5)(12) with zinc dichloride. It is mononuclear and the molecule is generated by twofold rotation symmetry. The central ZnIT atom is N,N'-chelated by each of the two N-silylated anilide ligands in a highly distorted tetrahedral environment. Two N-Si-N ligands are arranged in a cis fashion around the Zn-II atom. The Zn-N-amine bonds [2.2315 (12) angstrom] are much longer than the Zn-N-anilide bonds [1.9367 (11) angstrom].
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页码：M246 / U321
页数：7
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