SYNTHESIS AND STRUCTURE OF OCTAHEDRAL NICKEL(IV) COMPLEXES CONTAINING 2 CHELATING ACYLPHENOLATO LIGANDS

被引：11

作者：

KLEIN, HF

BICKELHAUPT, A

LEMKE, M

JUNG, T

ROHR, C

机构：

来源：

CHEMISTRY LETTERS | 1995年 / 06期

关键词：

D O I：

10.1246/cl.1995.467

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

2-Acylphenolato complexes Ni(C=O O)(PMe(3))(3) can be oxidized using iodine or diiodoalkanes at ambient conditions to afford ion-spin d(6) complexes Ni(C=O O)(2)(PMe(3))(2). The molecular structure of the 5-tert-butyl-3-methyl derivative contains two axial trimethylphosphines and a cisoidal arrangement of two acylphenolato dianions in equatorial positions.

引用

页码：467 / 468

页数：2

共 5 条

[1] SYNTHESES AND PROPERTIES OF THE 1ST OCTAHEDRAL DIORGANONICKEL(IV) COMPOUNDS [J].