A CYCLIC HEXAIRON(III) COMPLEX WITH AN OCTAHEDRALLY COORDINATED SODIUM-ION AT THE CENTER, AN EXAMPLE OF THE [12]METALLACROWN-6 STRUCTURE TYPE

被引：121
作者：
CANESCHI, A
CORNIA, A
LIPPARD, SJ
机构：
[1] MIT,DEPT CHEM,CAMBRIDGE,MA 02139
[2] UNIV FLORENCE,DIPARTIMENTO CHIM,I-50144 FLORENCE,ITALY
[3] UNIV MODENA,DIPARTIMENTO CHIM,I-41100 MODENA,ITALY
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 04期
关键词：
COMPLEXES WITH OXYGEN LIGANDS; HOST-GUEST CHEMISTRY; IRON COMPOUNDS; MAGNETIC PROPERTIES;
D O I：
10.1002/anie.199504671
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A crown composed purely of inorganic components forms the core of complex cation 1. Interest in this polyiron ion is based on its potential relevance to intermediates in the formation of the ferritin core and the hydrolytic polymerization of FeIII salts. The crown structure is supported by the inclusion of a sodium ion within the Fe6O6 ring. (Formula Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany
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页码：467 / 469
页数：3
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