X-RAY AND FOURIER-TRANSFORM INFRARED STUDIES OF 1,8-BIS(DIMETHYLAMINOMETHYL)NAPHTHALENE - COMPARISON WITH 1,8-BIS(DIMETHYLAMINO)NAPHTHALENE

被引：7

作者：

VANMEERVELT, L ^{[1
]}

PLATTEBORZE, K ^{[1
]}

ZEEGERSHUYSKENS, T ^{[1
]}

机构：

[1] CATHOLIC UNIV LEUVEN,DEPT CHEM,PHYS CHEM LAB,B-3001 LOUVAIN,BELGIUM

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1994年 / 05期

关键词：

D O I：

10.1039/p29940001087

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The X-ray structure of a proton sponge, 1,8-bis(dimethylaminomethyl)naphthalene (DMAMN) has been determined and its FTIR spectrum investigated. The results are compared with previously reported data on 1,8-bis(dimethylamino)naphthalene (DMAN). The X-ray results show that in DMAMN, the naphthalene ring is almost planar in contrast with DMAN; The IR spectra of these two molecules are markedly different and the decrease in the intensity of some ring and CH vibrational modes in DMAMN is discussed as a function of the high er symmetry of the naphthalene skeleton of the molecule.

引用

页码：1087 / 1090

页数：4

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