X-RAY AND FOURIER-TRANSFORM INFRARED STUDIES OF 1,8-BIS(DIMETHYLAMINOMETHYL)NAPHTHALENE - COMPARISON WITH 1,8-BIS(DIMETHYLAMINO)NAPHTHALENE

被引：7
|
作者：
VANMEERVELT, L [1 ]
PLATTEBORZE, K [1 ]
ZEEGERSHUYSKENS, T [1 ]
机构：
[1] CATHOLIC UNIV LEUVEN,DEPT CHEM,PHYS CHEM LAB,B-3001 LOUVAIN,BELGIUM
来源：
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1994年 / 05期
关键词：
D O I：
10.1039/p29940001087
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The X-ray structure of a proton sponge, 1,8-bis(dimethylaminomethyl)naphthalene (DMAMN) has been determined and its FTIR spectrum investigated. The results are compared with previously reported data on 1,8-bis(dimethylamino)naphthalene (DMAN). The X-ray results show that in DMAMN, the naphthalene ring is almost planar in contrast with DMAN; The IR spectra of these two molecules are markedly different and the decrease in the intensity of some ring and CH vibrational modes in DMAMN is discussed as a function of the high er symmetry of the naphthalene skeleton of the molecule.
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收藏
页码：1087 / 1090
页数：4
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