SYNTHESIS AND CHARACTERIZATION OF THE DOUBLE CLUSTER COMPLEXES OF [(MU-RS)(MU-MEAS)FE2 (CO)6]2 - THE CRYSTAL AND MOLECULAR-STRUCTURE OF [(MU-IPRS)(MU-MEAS)FE2(CO)6]2

被引：9

作者：

SONG, LC ^{[1
]}

HU, QM ^{[1
]}

HE, JL ^{[1
]}

WANG, RJ ^{[1
]}

WANG, HG ^{[1
]}

机构：

[1] NANKAI UNIV,CENT LAB,TIANJIN 300071,PEOPLES R CHINA

来源：

HETEROATOM CHEMISTRY | 1992年 / 3卷 / 5-6期

关键词：

D O I：

10.1002/hc.520030503

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By the reaction of [(mu-RS) (mu-CO)Fe2 (CO)6] [Et3NH] with MeASI2, six new double cluster complexes, [(mu-RS) (mu-MeAs)Fe2(CO)6]2 (R = Et, Pr, (i)Pr, Bu, C5H11, Ph), were synthesized. The structure of the (i)Pr analog was determined by single crystal X-ray diffraction techniques. Crystal data were as follows: monoclinic, P2(1)/n, Z = 4, a = 14.475(4), b = 13.825(3), c = 17.225(5) angstrom, beta = 112.44(2)-degrees, V = 3186 angstrom3, R = 0.037, and R(w) = 0.052.

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页码：465 / 469

页数：5

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