SYNTHESIS AND CHARACTERIZATION OF THE DOUBLE CLUSTER COMPLEXES OF [(MU-RS)(MU-MEAS)FE2 (CO)6]2 - THE CRYSTAL AND MOLECULAR-STRUCTURE OF [(MU-IPRS)(MU-MEAS)FE2(CO)6]2

被引：9
作者：
SONG, LC [1 ]
HU, QM [1 ]
HE, JL [1 ]
WANG, RJ [1 ]
WANG, HG [1 ]
机构：
[1] NANKAI UNIV,CENT LAB,TIANJIN 300071,PEOPLES R CHINA
来源：
HETEROATOM CHEMISTRY | 1992年 / 3卷 / 5-6期
关键词：
D O I：
10.1002/hc.520030503
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
By the reaction of [(mu-RS) (mu-CO)Fe2 (CO)6] [Et3NH] with MeASI2, six new double cluster complexes, [(mu-RS) (mu-MeAs)Fe2(CO)6]2 (R = Et, Pr, (i)Pr, Bu, C5H11, Ph), were synthesized. The structure of the (i)Pr analog was determined by single crystal X-ray diffraction techniques. Crystal data were as follows: monoclinic, P2(1)/n, Z = 4, a = 14.475(4), b = 13.825(3), c = 17.225(5) angstrom, beta = 112.44(2)-degrees, V = 3186 angstrom3, R = 0.037, and R(w) = 0.052.
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页码：465 / 469
页数：5
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