SYNTHESIS AND CHARACTERIZATION OF THE DOUBLE CLUSTER COMPLEXES OF [(MU-RS)(MU-MEAS)FE2 (CO)6]2 - THE CRYSTAL AND MOLECULAR-STRUCTURE OF [(MU-IPRS)(MU-MEAS)FE2(CO)6]2

被引：9

作者：

SONG, LC ^{[1
]}

HU, QM ^{[1
]}

HE, JL ^{[1
]}

WANG, RJ ^{[1
]}

WANG, HG ^{[1
]}

机构：

[1] NANKAI UNIV,CENT LAB,TIANJIN 300071,PEOPLES R CHINA

来源：

HETEROATOM CHEMISTRY | 1992年 / 3卷 / 5-6期

关键词：

D O I：

10.1002/hc.520030503

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By the reaction of [(mu-RS) (mu-CO)Fe2 (CO)6] [Et3NH] with MeASI2, six new double cluster complexes, [(mu-RS) (mu-MeAs)Fe2(CO)6]2 (R = Et, Pr, (i)Pr, Bu, C5H11, Ph), were synthesized. The structure of the (i)Pr analog was determined by single crystal X-ray diffraction techniques. Crystal data were as follows: monoclinic, P2(1)/n, Z = 4, a = 14.475(4), b = 13.825(3), c = 17.225(5) angstrom, beta = 112.44(2)-degrees, V = 3186 angstrom3, R = 0.037, and R(w) = 0.052.

引用

页码：465 / 469

页数：5

共 50 条

[21] NOVEL INTRAMOLECULAR CHEMISTRY INVOLVING THIOLATE, VINYL, AND CARBONYL LIGANDS IN REACTIONS OF ACETYLENES WITH LI[(MU-RS)(MU-CO)FE2(CO)6]
SEYFERTH, D
HOKE, JB
DEWAN, JC
[J]. ORGANOMETALLICS, 1987, 6 (04) : 895 - 897
[22] REACTIONS OF 2-FURYL, 2-THIENYL, AND N-METHYL-2-PYRROLYL MERCURIALS WITH [ET3NH][(MU-CO)(MU-RS)FE2(CO)6] COMPLEXES - SYNTHESIS OF FE2(CO)6 COMPLEXES WITH BRIDGING ETA(1)-ETA(2)-FURYL AND THIENYL LIGANDS
SEYFERTH, D
ANDERSON, LL
VILLAFANE, F
COWIE, M
HILTS, RW
[J]. ORGANOMETALLICS, 1992, 11 (10) : 3262 - 3271
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WANG, RJ
LIU, JT
WANG, HG
WANG, JT
[J]. ACTA CHIMICA SINICA, 1990, 48 (11) : 1141 - 1146
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SEYFERTH, D
HOKE, JB
WOMACK, GB
[J]. ORGANOMETALLICS, 1990, 9 (10) : 2662 - 2672
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SEYFERTH, D
RUSCHKE, DP
DAVIS, WM
COWIE, M
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[J]. ORGANOMETALLICS, 1994, 13 (10) : 3834 - 3848
[26] REACTIONS OF [ET3NH][(MU-CO)(MU-RS)FE2(CO)6] COMPLEXES WITH THIAZOLYL-MERCURIALS, OXAZOLYL-MERCURIALS AND IMIDAZOYL-MERCURIALS - A ROUTE TO FE2(CO)6 COMPLEXES CONTAINING AN ETA(1), ETA(2)-C=N BRIDGE
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ANDERSON, LL
DAVIS, WM
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 459 (1-2) : 271 - 281
[27] SYNTHESIS OF COMPLEXES FE2(NO)4(MU-SR)(MU-NHR') BY THE SEQUENCE REDUCTION-ALKYLATION OF FE2(NO)4(MU-SR)2
CHAU, CN
WOJCICKI, A
[J]. BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY, 1994, 42 (03): : 323 - 333
[28] REGIOSELECTIVITY AND STEREOSELECTIVITY OF HALOGEN SUBSTITUTION IN FE2(CO)6(MU-PRCL)(MU-HAL)
EVERTZ, K
HUTTNER, G
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[29] REACTION OF SOME ELECTROPHILES WITH ET3NH[MU-CO)(MU-RS)FE2(CO)6] AND SYNTHESIS OF MIXED-LIGANDS BRIDGED DIIRON CARBONYL-COMPLEXES
SONG, LC
LI, Y
HU, QM
LIU, RG
WANG, JT
[J]. ACTA CHIMICA SINICA, 1990, 48 (12) : 1180 - 1184
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CHANG, SC
KAFAFI, ZH
HAUGE, RH
WHITMIRE, KH
BILLUPS, WE
MARGRAVE, JL
[J]. INORGANIC CHEMISTRY, 1986, 25 (25) : 4530 - 4533

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