ON PREPARATION AND STRUCTURE OF ACETAMIDINIUM TETRACHLOROCUPRATE(2)

被引:13
作者
BARES, LA
EMERSON, K
DRUMHELL.JE
机构
[1] Chemistry and Physics, Montana State University, Bozeman
关键词
D O I
10.1021/ic50071a030
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Acetamidinium tetrachlorocuprate has been prepared and characterized. Optical spectra, thermochromism, and epr spectra of this compound are reported and discussed. A structural model is proposed in which CuCl2-4 layers are composed of strips of tetrahedral sites alternated with strips of tetragonal sites. These layers are separated from each other by the acetamidinium ions. © 1969, American Chemical Society. All rights reserved.
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页码:131 / &
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共 12 条
[1]  
BONAMICO M, 1966, ACTA CRYSTALLOGR A, V21, P136
[2]   ELECTRONIC ABSORPTION SPECTRUM + STRUCTURE OF CUCL4EQUAL [J].
FERGUSON, J .
JOURNAL OF CHEMICAL PHYSICS, 1964, 40 (11) :3406-&
[3]   SPECTRAL + MAGNETIC PROPERTIES OF CHLOROCUPRATES [J].
HATFIELD, WE ;
PIPER, TS .
INORGANIC CHEMISTRY, 1964, 3 (06) :841-&
[4]   THE CRYSTAL STRUCTURE OF CESIUM CHLOROCUPRATE, CS2CUCL4, AND THE SPECTRUM OF THE CHLOROCUPRATE ION [J].
HELMHOLZ, L ;
KRUH, RF .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1952, 74 (05) :1176-1181
[5]   CONFIGURATION OF TETRACHLOROCUPRATE(II) ION [J].
MOROSIN, B ;
LINGAFELTER, EC .
JOURNAL OF PHYSICAL CHEMISTRY, 1961, 65 (01) :50-&
[6]   Chloro complex salts of the two valent cooper [J].
Remy, H ;
Laves, G .
BERICHTE DER DEUTSCHEN CHEMISCHEN GESELLSCHAFT, 1933, 66 :401-407
[9]   CRYSTAL STRUCTURE OF (NH4)2CUCI4 [J].
WILLETT, RD .
JOURNAL OF CHEMICAL PHYSICS, 1964, 41 (08) :2243-&
[10]   ELECTRONIC ABSORPTION SPECTRA OF MONOMERIC COPPER(2) CHLORIDE SPECIES AND ELECTRON SPIN RESONANCE SPECTRUM OF SQUARE-PLANAR CUCL42-ION [J].
WILLETT, RD ;
LILES, OL ;
MICHELSO.C .
INORGANIC CHEMISTRY, 1967, 6 (10) :1885-&