A PREPARATION OF N,N-BIS(TRIMETHYLSILYL)ALLENAMINES

被引：3
|
作者：
CUNICO, RF
KUAN, CP
机构：
[1] Department of Chemistry, Northern Illinois University, DeKalb
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 487卷 / 1-2期
关键词：
SILICON; CARBANIONS; ALLENE; SILYL; AMINE; TRIMETHYLSILYL;
D O I：
10.1016/0022-328X(94)05068-M
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The lithium diisopropylamide-induced elimination of {2-[N,N-bis(trimethylsilyl)amino]alkenyl}(diethyl)phosphates affords 1-[N,N-bis(trimethylsilyl)amino]-1,2-alkadienes (''allenamines''). Conjugatively-substituted allenamines undergo further metalation under these eliminative conditions to form allenyl carbanions which may be trapped in situ by chlorotrimethylsilane to give 3-trimethylsilyl- or 3,3-bis(trimethylsilyl)-N, N-bis(trimethylsilyl)allenamines.
引用
收藏
页码：89 / 93
页数：5
相关论文
共 50 条
  • [41] An improved preparation of tris(trimethylsilyl)heptaphosphine
    Schmidbaur, H
    Bauer, A
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1995, 102 (1-4): : 217 - 219
  • [42] Preparation of β-Lactams by Mannich-Type Addition of Ethyl(trimethylsilyl)acetate (ETSA) to N-(2-Hydroxyphenyl)aldimine Sodium Salts
    Gembus, Vincent
    Poisson, Thomas
    Oudeyer, Sylvain
    Marsais, Francis
    Levacher, Vincent
    SYNLETT, 2009, (15) : 2437 - 2440
  • [43] Optimization of parameters for the preparation of AlN powder/thin films by tris(N,N,n',n'-tetramethylethylenediamine) al(III) chloride precursor
    Chaurasia, Himanshi
    Tripathi, Santosh K.
    Bilgaiyan, Kamlesh
    Dwivedi, Mayank
    JOURNAL OF COORDINATION CHEMISTRY, 2024, 77 (20-21) : 2453 - 2471
  • [44] Preparation, Structural Determination, and Characterization of Electronic Properties of Bis-silylated and Bis-germylated Lu3N@Ih-C80
    Kako, Masahiro
    Miyabe, Kyosuke
    Sato, Kumiko
    Suzuki, Mitsuaki
    Mizorogi, Naomi
    Wang, Wei-Wei
    Yamada, Michio
    Maeda, Yutaka
    Olmstead, Marilyn M.
    Balch, Alan L.
    Nagase, Shigeru
    Akasaka, Takeshi
    CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (46) : 16411 - 16420
  • [45] Bis-(1,2-N,N-dimethylaminomethylferrocenyl)dichlorosilane -: structure and reactivity
    Palitzsch, W
    Pietzsch, C
    Puttnat, M
    Jacob, K
    Merzweiler, K
    Zanello, P
    Cinquantini, A
    Fontani, M
    Roewer, G
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 587 (01) : 9 - 17
  • [46] 2,5''-bis-(N,N-dimethylaminomethyl)ferrocenyl formation and structure
    Jacob, K
    Merzweiler, K
    Thiele, KH
    Voigt, F
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 526 (01) : 191 - 194
  • [47] Novel method for preparing bis(trimethylsilyl)amines via treatment with trimethylsilylamines and methyl iodide
    Hamada, Y
    Yamamoto, Y
    Shimizu, H
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 510 (1-2) : 1 - 6
  • [48] Preparation, characterization and properties of dipolar 1,2-N,N-dimethylaminomethylferrocenylsilanes
    Beyer, C
    Böhme, U
    Pietzsch, C
    Roewer, G
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 654 (1-2) : 187 - 201
  • [49] New Method of Tris(trimethylsilyl) Antimonite Preparation
    Basenko, S. V.
    Voronkov, M. G.
    Cao Meihua
    Gebel, I. A.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2008, 78 (08) : 1633 - 1634
  • [50] New method of tris(trimethylsilyl) antimonite preparation
    S. V. Basenko
    M. G. Voronkov
    Cao Meihua
    I. A. Gebel’
    Russian Journal of General Chemistry, 2008, 78 : 1633 - 1634
12345