4-[Amino(3-methylphenyl)methylidene]-2-(3-methylphenyl)-1H-imidazol-5(4H)-one ethanol hemisolvate

被引：0

作者：

Prabhuswamy, M. ^{[1
]}

Kumar, S. Madan ^{[1
]}

Muneer, C. P. ^{[2
]}

Shafi, P. M. ^{[2
]}

Lokanath, N. K. ^{[1
]}

机构：

[1] Univ Mysore, Dept Studies Phys, Mysore 570006, Karnataka, India

[2] Calicut Univ, Dept Chem, Calicut 673635, Kerala, India

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷

关键词：

data-to-parameter ratio = 15.1; mean σ(C-C) = 0.004 Å; R factor = 0.070; single-crystal X-ray study; T = 300 K; wR factor = 0.227;

D O I：

10.1107/S160053681205163X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, C18H17N3O center dot 0.5C(2)H(5)OH, the dihedral angles between the central imidazole rings and the pendant benzene rings are 42.06 (15) and 2.01 (16)degrees in one asymmetric molecule and 47.91 (15) and 7.31 (14)degrees in the other. An intramolecular N-H center dot center dot center dot O hydrogen bond occurs in each imidazole molecule. In the crystal, the components are connected by O-H center dot center dot center dot N, N-H center dot center dot center dot O, C-H center dot center dot center dot O and NH center dot center dot center dot N hydrogen bonds. Weak aromatic pi-pi interactions also occur [ shortest centroid-centroid distance = 3.684 (3) (A) over circle].

引用

页码：O174 / +

页数：12

共 6 条

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