4-Phenyl-1H-1,5-benzodiazepin-2(3H)-one

被引：4

作者：

Akkurt, Mehmet ^{[1
]}

Kennedy, Alan R. ^{[2
]}

Younes, Sabry H. H. ^{[3
]}

Mohamed, Shaaban K. ^{[4
,5
]}

Abdelhamid, Antar A. ^{[4
]}

机构：

[1] Erciyes Univ, Fac Sci, Dept Phys, TR-38039 Kayseri, Turkey

[2] Univ Strathclyde, Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland

[3] Sohag Univ, Fac Sci, Dept Chem, Sohag 82524, Egypt

[4] Manchester Metropolitan Univ, Chem & Environm Div, Manchester M1 5GD, Lancs, England

[5] Menia Univ, Fac Sci, Dept Chem, El Minia 61519, Egypt

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷

关键词：

data-to-parameter ratio = 15.5; mean ω(C-C) = 0.003 Å; R factor = 0.053; single-crystal X-ray study; T = 123 K; wR factor = 0.140;

D O I：

10.1107/S160053681204651X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, C15H12N2O, the phenyl ring makes a dihedral angle of 32.45 (9)degrees with the benzene ring of the 1,5-benzodiazepin-2-one unit. The seven-membered ring adopts a boat conformation with the methylene group as the prow and the fused benzene-ring C atoms as the stern. In the crystal, inversion dimers linked by pairs of N-H center dot center dot center dot O hydrogen bonds generate R-2(2)(8) loops. The dimers are further linked by CH center dot center dot center dot O hydrogen bonds, so forming a column along the a-axis direction.

引用

页码：O3356 / +

页数：7

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