(1H-Pyrazole-kappa N)bis(tri-tert-butoxy-silanethiolato-kappa O-2,S)cadmium

被引：3
作者：
Baranowska, Katarzyna [1 ]
Bulman, Mateusz [1 ]
Dolega, Anna [1 ]
机构：
[1] Gdansk Univ Technol, Fac Chem, Dept Inorgan Chem, 11-12 G Narutowicz St, PL-80233 Gdansk, Poland
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词：
data-to-parameter ratio = 17.1; disorder in main residue; mean ω(C-C) = 0.005 Å; R factor = 0.039; single-crystal X-ray study; T = 120 K; wR factor = 0.103;
D O I：
10.1107/S1600536812047186
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The Cd II atom in the title complex, [Cd(C12H27O3SSi)(2)-( C3H4N2)], is penta-coordinated by two O and two S atoms from the O, S-chelating silanethiolate residue and one pyrazole N atom in a distorted geometry that is slightly closer to trigonal-bipyramidal than to square-based pyramidal. The pyrazole ligand is stabilized within the complex by an intramolecular N-H center dot center dot center dot O hydrogen bond. One of the tertbutyl groups is disordered over two orientations with occupancy ratio of 0.534 (6): 0.466 (6).
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页码：M1515 / +
页数：13
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