COORDINATION CHEMISTRY OF BIS(3-AMINOPROPYL)PHENYLPHOSPHINE (BAP) - REACTIONS OF BAP WITH SOME D6 METAL-COMPLEXES OF MOLYBDENUM(0), TUNGSTEN(0) AND PLATINUM(IV)

被引：12

作者：

BECKETT, MA

CASSIDY, DP

DUFFIN, AJ

机构：

[1] Department of Chemistry, University of Wales, Bangor

来源：

INORGANICA CHIMICA ACTA | 1991年 / 189卷 / 02期

关键词：

D O I：

10.1016/S0020-1693(00)80193-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Bis(3-aminopropyl)phenylphosphine (bap) has been reacted with fac-[{PtMe3I}4] in CHCl3 solution to yield fac-[PtMe3(bap)]I which has the bap ligand tridentate NNP. Metathesis of fac-[PtMe3(bap)]I with Na[BPh4] in thf solution results in fac-[PtMe3(bap)][BPh4]. Bap is also NNP tridentate in the Group 6 metal(0) complexes fac-[Mo(CO)3(bap)] and fac-[W(CO)3(bap)], prepared from the reactions of bap with cis-[M(CO)4(pip)2] (M = Mo, W). The new complexes have been characterized by melting point, elemental analysis, and by IR and multielement (H-1, B-11, P-31) NMR spectroscopy.

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页码：229 / 232

页数：4

相关论文

共 20 条

[1] SUBSTITUTED CARBONYL COMPOUNDS OF CHROMIUM, MOLYBDENUM, TUNGSTEN, AND MANGANESE [J].

ABEL, EW ;

BENNETT, MA ;

WILKINSON, G .

JOURNAL OF THE CHEMICAL SOCIETY, 1959, (JUL-A) :2323-2327

[2] TRIMETHYLPLATINUM(IV) COMPLEXES OF THE DIMETHYLDITHIOARSINATE(V) ANION - PREPARATION AND MOLECULAR-STRUCTURE OF THE DINUCLEAR [(PTME3)2(ME2ASS2)2] AND ITS SELECTIVE FISSION TO MONONUCLEAR [PTME3(ME2ASS2)PPH3], [PTME3(ME2ASS2)PPH2ME], [PTME3(ME2ASS2)PY] COMPLEXES [J].

ABEL, EW ;

BECKETT, MA ;

BATES, PA ;

HURSTHOUSE, MB .

POLYHEDRON, 1988, 7 (19-20) :1855-1859

[3] IMPROVED ISOLATION PROCEDURE FOR PREPARATION OF IODO(TRIMETHYL)PLATINUM(IV) [J].

BALDWIN, JC ;

KASKA, WC .

INORGANIC CHEMISTRY, 1975, 14 (08) :2020-2020

[4] CONVENIENT SYNTHESIS OF CIS-MO(CO)4L2 DERIVATIVES (L = GROUP 5A LIGAND) AND A QUALITATIVE STUDY OF THEIR THERMAL REACTIVITY TOWARD LIGAND DISSOCIATION [J].

DARENSBOURG, DJ ;

KUMP, RL .

INORGANIC CHEMISTRY, 1978, 17 (09) :2680-2682

[5] NATURE OF SOLUTIONS OF METHYLMERCURY (II), DIMETHYLGOLD-(III), AND TRIMETHYLPLATINUM(IV) IN PYRIDINE AND LIQUID-AMMONIA - LIGAND-EXCHANGE IN UNSYMMETRICAL DIMETHYLGOLD(III) COMPLEXES [J].

HAGNAUER, H ;

STOCCO, GC ;

TOBIAS, RS .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1972, 46 (01) :179-&

[6]

HAINES LM, 1969, ADV INORG CHEM RAD, V12, P53

[7] STUDY OF SOME AMINE, PYRIDINE AND 3,5-LUTIDINE COMPLEXES OF TRIMETHYLPLATINUM(IV) [J].

HALL, JR ;

SWILE, GA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1972, 42 (02) :479-&

[8]

Hartley F. R, 1982, COMPREHENSIVE ORGANO, P471

[9] MIXED COMPLEXES OF GROUP 4B METAL CARBONYLS [J].

HOUK, LW ;

DOBSON, GR .

INORGANIC CHEMISTRY, 1966, 5 (12) :2119-&

[10]

House D. A., 1987, COMPREHENSIVE COORDI, V2, P23