NEW METHOD FOR THE PREPARATION OF HYDRODESULFURIZATION CATALYSTS - USE OF THE MOLYBDENUM SULFUR CLUSTER COMPOUND (NH4)2[MO3IVS13]

被引：50
作者：
MULLER, A
DIEMANN, E
BRANDING, A
BAUMANN, FW
BREYSSE, M
VRINAT, M
机构：
[1] UNIV CLAUDE BERNARD LYON 1, INST RECH CATALYSE, CNRS, 2 AVE ALBERT EINSTEIN, F-69626 VILLEURBANNE, FRANCE
[2] UNIV BIELEFELD, FAC CHEM, W-4800 BIELEFELD, GERMANY
来源：
APPLIED CATALYSIS | 1990年 / 62卷 / 01期
关键词：
Ammonium Molybdate - Ammonium Thiomolybdate - Hydrodesulfurization Catalysts;
D O I：
10.1016/S0166-9834(00)82228-9
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In order to overcome existing difficulties, it would make sense to use datalytic precursors already in the sulphided state. Such an approach was used successfully by us in the case of unsupported mixed catalysts prepared by decomposition if bisthiometalato complex. An other method which appears very promising and general for the preparation of sulphide catalysts is described. This method consists in the direct use of metal sulphur cluster (NH4)2Mo3(S) (S2)6[ as precursor for the preparation of molybdenum sulphide based catalysts. It is shown that the utilization of a complex presenting structural and electronic similarities to the MoS2 phase allows the preparation of highly active catalyst. This method should be suitable for other supports and other active phases (e.g. tungsten).
引用
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页码：L13 / L17
页数：5
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