MAGNETIC STUDIES OF CHROMIUM(II) AND CHROMIUM(III) METALLOCARBORANES

被引：6

作者：

CRAWFORD, VH

HATFIELD, WE

SALENTINE, CG

CALLAHAN, KP

HAWTHORNE, MF

机构：

[1] UNIV CALIF LOS ANGELES,DEPT CHEM,LOS ANGELES,CA 90024

[2] UNIV N CAROLINA,DEPT CHEM,CHAPEL HILL,NC 27514

来源：

INORGANIC CHEMISTRY | 1979年 / 18卷 / 06期

关键词：

D O I：

10.1021/ic50196a043

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Temperature-dependent magnetic susceptibility data for [(C2H5)4N]2[CrII(C2B10H12] have been collected in the range 1.4-80 K. The magnetic data may be fit to the Curie-Weiss law x = C/(T-θ) with g = 2.00 and θ = -1.7 K. Magnetic data for Cs[CrIII(C2B9H11)2] yield g = 1.98 and θ = -1.5 K, in excellent agreement with results from EPR studies. The deviations from the Curie law, as indicated by the θ values, are thought to arise from single-ion effects. © 1979, American Chemical Society. All rights reserved.

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页码：1600 / 1603

页数：4

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